Organisation/Company: Institut des Sciences Chimiques de Rennes UMR 6226 CNRS - Université de Rennes 1
Research Field: Engineering Chemistry
Researcher Profile: Recognised Researcher (R2), Leading Researcher (R4), First Stage Researcher (R1), Established Researcher (R3)
Country: France
Application Deadline: 29 Apr 2025 - 22:00 (UTC)
Type of Contract: Temporary
Job Status: Full-time
Offer Starting Date: 1 Sep 2025
Is the job funded through the EU Research Framework Programme? Not funded by a EU programme
Is the Job related to staff position within a Research Infrastructure? No
The Oxymore project involves the reuse of wastewater in coastal areas, as part of the first indirect drinking water production demonstrator in Europe, commissioned by Vendée Eau. Indirect drinking water treatment involves the replenishment of surface water reserves with finely-treated wastewaters, which are then used to supply drinking water production plants. Consequently, the production of high-quality, pathogen-free water containing low concentrations of trace organic contaminants (TrOCs) is necessary.
The project aims to evaluate two hybrid ozonation-nanofiltration (HONF) processes as more sustainable alternatives to the low-pressure reverse osmosis (LPRO) used on the demonstrator, in order to minimize energy and environmental footprints. HONF involves the simultaneous oxidative degradation and retention of organic matter and TrOCs. The added value of this coupling lies in its ability to reduce the drawbacks of each process, in particular a decrease of the membrane fouling and the rejection of the oxidation by-products formed during the ozonation stage.
The first HONF process, developed by the IEM Montpellier, uses ozone-enriched gas bubbles introduced into the NF cell containing a catalytic ceramic membrane. The second process, developed in Rennes, uses pre-ozonated water mixed with H2O2-doped wastewater, leaving the door open to the use of organic membranes. It is more specifically on this second process that the doctoral student recruited will be involved.
A detailed characterisation (ions, TrOCs, organic matter) of the effluent to be treated, taking into account seasonal variations, will be carried out. The organic matter in the effluent will be fractionated and carefully analysed by the IC2MP in Poitiers. Lyophilized fractions will then be used to construct a synthetic water model, with a chemical composition identical to that of the industrial effluent. This synthetic water model will be used at the beginning of the thesis for a laboratory study dedicated to the optimization of the HONF process.
A scale-up will then be carried out on-site with monitoring for several months in parallel with the existing LPRO process. Detailed characterization of the organic matter and its evolution during the treatment will enable the rejection and oxidation mechanisms to be identified and understood. Mass spectrometry will be implemented to assess TrOCs removal efficiency and the formation of oxidation by-products. These chemical analyses will be combined with bioassays (carried out by INSERM Montpellier) to monitor the toxicity and ecotoxicity of the feed and of the permeates and retentates produced on-site. In addition to the validation of the performances of each configuration on real wastewater, these long-term tests will allow to assess the ageing of the membranes and set up cleaning in place procedures.
These characterisations will be used as inputs for a technico-economic study (carried out as part of this thesis) and an environmental impact study (carried out by UniLasalle Rennes).
This doctoral contract is funded by the French National Research Agency (OXYMORE collaborative research project – 670 kEuros). The Oxymore project brings together the expertise of 5 public and private academic teams:
Within this consortium, Vendée Eau, the public company responsible for managing and distributing drinking water throughout the Vendée department, occupies a central position.
5 years' higher education (engineering school and/or Masters II) in process engineering and/or water chemistry. At least theoretical knowledge of analytical chemistry (liquid chromatography, ion chromatography, mass spectrometry, etc.) is also required, and practical experience in HPLC would also be appreciated.
Particular attention will be paid to the experimental skills of the candidate, who should have done sufficient practical chemistry work during their training.
Motivation for academic research.
Good communication and coordination skills with different partners.
Fluency in French and English (written and spoken). B2 level required.
Ability to present results both orally and in writing.
Ability to summarise (a bibliographic summary is required).
Willingness to travel (a period of several months on-site in Les Sable d'Olonne is required). Driving licence would be appreciated.
Number of offers available: 1
Company/Institute: Institut des Sciences Chimiques de Rennes UMR 6226 CNRS - Université de Rennes 1
Country: France
City: Rennes